全文获取类型
收费全文 | 4030篇 |
免费 | 157篇 |
国内免费 | 12篇 |
专业分类
化学 | 2653篇 |
晶体学 | 38篇 |
力学 | 66篇 |
数学 | 434篇 |
物理学 | 1008篇 |
出版年
2023年 | 41篇 |
2022年 | 41篇 |
2021年 | 123篇 |
2020年 | 103篇 |
2019年 | 120篇 |
2018年 | 95篇 |
2017年 | 101篇 |
2016年 | 173篇 |
2015年 | 129篇 |
2014年 | 128篇 |
2013年 | 245篇 |
2012年 | 270篇 |
2011年 | 332篇 |
2010年 | 202篇 |
2009年 | 207篇 |
2008年 | 289篇 |
2007年 | 259篇 |
2006年 | 209篇 |
2005年 | 186篇 |
2004年 | 172篇 |
2003年 | 121篇 |
2002年 | 97篇 |
2001年 | 73篇 |
2000年 | 71篇 |
1999年 | 43篇 |
1998年 | 27篇 |
1997年 | 33篇 |
1996年 | 31篇 |
1995年 | 29篇 |
1994年 | 23篇 |
1993年 | 25篇 |
1992年 | 30篇 |
1991年 | 14篇 |
1990年 | 16篇 |
1989年 | 13篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1984年 | 12篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 9篇 |
1978年 | 5篇 |
1977年 | 7篇 |
1976年 | 4篇 |
1975年 | 6篇 |
1974年 | 7篇 |
1972年 | 4篇 |
1968年 | 4篇 |
排序方式: 共有4199条查询结果,搜索用时 15 毫秒
991.
M. Dos Santos Afonso Cecilia Di Risio M. Zysmilich Roberto O. Marqués M.A. Blesa 《Radiation Physics and Chemistry》1996,48(6):715-718
The influence of gamma and reactor (n + γ) preirradiation on the dissolution of magnetite microcrystals synthetized by a low-temperature wet method was studied. Two opposite effects affect the dissolution rate: the annealing due to the gamma radiation and the generation of new imperfect coordination polyhedra. A model for the kinetic processes was proposed and the kinetic parameters were calculated. 相似文献
992.
Beta2-agonist extraction procedures for chromatographic analysis 总被引:1,自引:0,他引:1
dos Ramos FJ 《Journal of chromatography. A》2000,880(1-2):69-83
Normally, different procedures were necessary to prepare sample matrices for chromatographic determination of β2-agonists. The present review includes sampling, pre-treatment and extraction/purification for urine, plasma, liver, meat, feeds, hair and milk powder, as previous steps for chromatographic analysis of β2-agonists. Six methodologies were especially revised for extraction/purification namely, liquid–liquid extraction, solid-phase extraction (SPE), matrix solid-phase dispersion, immunoaffinity chromatography, dialysis and supercritical fluid extraction. SPE was discussed in detail and five mechanisms were described: adsorption, apolar, polar, ion-exchange and mixed phase. A brief conclusion in this field was also outlined. 相似文献
993.
A new flexible approach to hexahydropyrrolo[2,3-b]indole system via the [3,3]-sigmatropic rearrangement of 1-(2′-methoxycarbonyl-N-methylvinylamino)skatole, culminating in the synthesis of (±)-desoxyeseroline, is described. 相似文献
994.
Santos JP Corpart P Wong K Galembeck F 《Langmuir : the ACS journal of surfaces and colloids》2004,20(24):10576-10582
Low-Tg styrene-butadiene (SB) latex films were investigated by noncontact atomic force microscopy and scanning electric potential microscopy, revealing a number of different morphologies and electric potential patterns across films cast from the same SB latex dispersions under the same conditions. Surface leveling and charge dispersion throughout the films are, thus, restrained even at temperatures above Tg and the minimum film-formation temperature. An unprecedented electric pattern is observed, in which the particle cores are more positive than the contacting particle outer layers. Different packing patterns, including cubic and hexagonal arrays, coexist in neighboring areas. Zonal centrifugation of the SB latex in sucrose density gradient shows that particles cover a broad range of densities. Thus, film surface heterogeneity is at least partly due to particle heterogeneity. Fractal dimensions of topographic profiles are lower than those of the electric potential profiles, showing that charge mobility is much more restrained than polymer chain motion at the film surface and that it imposes a limit to the charged chain-ends motion. 相似文献
995.
996.
Arribas C Carreño MC García-Ruano JL Rodríguez JF Santos M Sanz-Tejedor MA 《Organic letters》2000,2(20):3165-3168
Hetero Diels-Alder (HDA) cycloaddition of chiral 1-p-tolylsulfinyl-1,3-pentadiene with benzyl nitrosoformate, under mild conditions, yields 2H-1,2-oxazine 3 with complete regioselectivity and pi-facial diastereoselectivity. Sequential osmylation and protection of the resulting glycol gives the oxazine 5 which is directly transformed into enantiomerically pure 1,4,5-trideoxy-1,4-imino-L-ribitol 8 by reduction under Pd/C. 相似文献
997.
998.
999.